Winter
is a tough season on anything exposed to the elements. Plants die. Animals
hibernate. Waterways get caught in a messy game of freeze and thaw.
But
our roads also bear winter’s brunt.
And
it’s not snow and ice that are the biggest problem—it’s what we do to remove
them.
Winter
moisture alone already does a number on concrete by itself, as water—snow melt,
sleet, runoff—expands 9 percent its original size when frozen. That means when
concrete freezes, any moisture in the concrete can create pressure in the pores
of the concrete. When this pressure exceeds the concrete’s tensile capacity, it
causes cracking and spalling of the concrete surface.
If
large aggregate in the concrete is porous or absorptive, the moisture in the
aggregate can freeze and crack and split. If these aggregates are close to the
surface, they can create pop outs that look like cone shaped indentions on the
surface of the concrete. This cracking can also create D-cracking, which is
closely spaced cracks that parallel joints. These cracks will continue to
multiply over time and show up further and further from the joint.
Deicing
chemicals can make this process worse in different ways.
First,
the deicing chemicals reduce the freezing temperature of the offending
moisture. So rather than the moisture in the concrete freezing at 32 degrees
and staying frozen until the concrete temperature exceeds 32 degrees, it thaws
at a lower temperature and refreezes at a lower temperature. Therefore, the
concrete goes thru more freeze/thaw cycles than it would have if deicing
chemicals were not used. Each time the concrete freezes, it repeats the
expansion pressure that can create more cracking and spalling.
Most
deicing chemicals contain chlorides. These chlorides are like sponges that
attract and hold moisture. Therefore, concrete that is more saturated with
chlorides is probably more saturated with moisture and thus more susceptible to
damage when the concrete freezes.
Even
worse, certain deicing chemicals can actually chemically attack concrete. Deicers
containing ammonium nitrate and ammonium sulfate aggressively attack and
disintegrate concrete.
But
that’s not where the wear and tear stops. The same chlorides that weaken
concrete also bombard metal with enough moisture that it will rust—a huge
problem when you’re talking about concrete reinforced with metal. When metal
rusts, the rust can become four times larger than the original metal, causing
the concrete it is reinforcing to expand and crack. And once this process
starts, both the concrete and the steel deteriorate even faster than before.
There
are various ways to protect concrete and steel from winter’s ways—air
entrainment, low permeability in concrete, etc.—but the best thing for our
roads can hope for in the winter? No moisture.
Let
it snow? Not if you’re a road.
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